Dataset: Alkali Ion diffusion and structure of chemically strengthened TiO2 doped soda-lime silicate glass
type: Dataset
description: Diffusion kinetics and structural properties of chemically strengthened titania-doped soda-lime silicate glasses were studied by depth-resolved X-ray photoelectron spectroscopy, Raman spectroscopy and spectrophotometry. Chemical strengthening (CS) is frequently used to strengthen thin glasses. CS of glass is based on ion exchange of larger ions from a molten salt into glass. Both the ion and counter ion are conventionally monovalent alkali ions. Diffusion kinetics and structural properties of chemically strengthened titania-doped (TiO2) soda-lime silicate (SLS) glasses were studied by depth-resolved X-ray photoelectron spectroscopy, Raman spectroscopy and spectrophotometry. The glasses were ion exchanged, whereby Na+ in the glass was replaced by K+ in a molten salt bath, at four different treatment temperatures between 350 and 500 °C. The following samples were prepared and analyzed by X-ray Photoelectron Spectroscopy (XPS): (1) SLS, (2) 4.7% TiO2, and (3) 9.9% TiO2. The ion exchange procedure was performed for 5 h at four different temperatures below Tg (350, 400, 450 and 500 °C). Before XPS measurements, the samples were wet-etched using hydrofluoric (HF) acid to produce samples with six different etching depths. The Raman scattered light was detected in the backscattering configuration employing linear polarization and 2400 lines/mm grating, and a 100x objective lens. Depth profile spectra were collected at six different depths of 0, 10, 20, 30, 40, and 50 µm for each glass sample, employing 12 scans with a 10 s exposure time for each scan. Spectrophotometric measurements were conducted before and after K+/Na+ ion-exchange treatmeatment for 5 h at 500 °C, collected between 300 and 2500 nm. File List: XPS: XPS_4.7%TiO2_350degrees_acq1.txt XPS_4.7%TiO2_350degrees_acq2.txt XPS_4.7%TiO2_400degrees_acq1.txt XPS_4.7%TiO2_400degrees_acq2.txt XPS_4.7%TiO2_450degrees_acq1.txt XPS_4.7%TiO2_450degrees_acq2.txt XPS_4.7%TiO2_500degrees_acq1.txt XPS_4.7%TiO2_500degrees_acq2.tx…
citation: CreativeWork
  name: Bengtsson, F., Pehlivan, I. B., Österlund, L., & Karlsson, S. (2022). Alkali ion diffusion and structure of chemically strengthened TiO2 doped soda-lime silicate glass. In Journal of Non-Crystalline Solids (No. 121564; Vol. 586, pp. 121564–121564). https://doi.org/10.1016/j.jnoncrysol.2022.121564
conditions of access: http://publications.europa.eu/resource/authority/access-right/PUBLIC
conditions of access: info:eu-repo/semantics/openAccess
creative work status: completed
  type: DefinedTerm
  in defined term set: http://publications.europa.eu/resource/authority/dataset-status
  term code: COMPLETED
creator: Felix Bengtsson
  type: Person
  affiliation: Uppsala University
  family name: Bengtsson
  given name: Felix
creator: Ilknur Bayrak Pehlivan
creator: Lars Österlund
creator: Stefan Karlsson
date modified: 2022-04-01
date published: 2022-04-01
funding: Tunnare och starkare glas för hållbar produktion och konsumtion
  type: Grant
  funder: FORMAS
language: English
is part of: https://doi.org/10.5878/jxpa-0k68
keywords: Condensed Matter Physics
  type: DefinedTerm
  description: Including: Materials Physics, Nano Physics
  term code: 10304
keywords: Analytical Chemistry
  type: DefinedTerm
  term code: 10401
keywords: Materials Chemistry
  type: DefinedTerm
  term code: 10403
keywords: Other Materials Engineering
  type: DefinedTerm
  term code: 20599
keywords: Spectrophotometry
keywords: Spectrum Analysis, Raman
keywords: Photoelectron Spectroscopy
keywords: diffusion
keywords: glass
keywords: melting
keywords: tempering (metalwork)
license: https://creativecommons.org/licenses/by/4.0/
publisher: RISE Research Institutes of Sweden
distribution: data/DATA 2022-4.zip
  type: DataDownload
  additional type: data
  conditions of access: http://publications.europa.eu/resource/authority/access-right/PUBLIC
  conditions of access: info:eu-repo/semantics/openAccess
  content size: 438032
  encoding format: application/zip
distribution: documentation/DATASET_README.pdf
  type: DataDownload
  additional type: documentation
  conditions of access: http://publications.europa.eu/resource/authority/access-right/PUBLIC
  conditions of access: info:eu-repo/semantics/openAccess
  content size: 180766
  encoding format: application/pdf
version: 1

PropertyValue
property ID: DOI
value: 10.5878/m3y0-kv73

principalRegistrationNumber
type: PropertyValue
property ID: https://www.rikstermbanken.se/termposter/1848/diarienummer
value: P105190

PropertyValue
property ID: DOI
value: 10.1016/j.jnoncrysol.2022.121564

PropertyValue
property ID: URN
value: urn:nbn:se:ri:diva-58914

Uppsala University
type: Organization
department: Department of Materials Science and Engineering, The Ångström Laboratory

Ilknur Bayrak Pehlivan
type: Person
affiliation: Uppsala University
family name: Pehlivan
given name: Ilknur Bayrak

Lars Österlund
type: Person
affiliation: Uppsala University
family name: Österlund
given name: Lars

Stefan Karlsson
type: Person
affiliation: RISE Research Institutes of Sweden
family name: Karlsson
given name: Stefan

RISE Research Institutes of Sweden
type: Organization

FORMAS
type: Organization

English
type: Language
alternate name: eng

Spectrophotometry
type: DefinedTerm
description: The art or process of comparing photometrically the relative intensities of the light in different parts of the spectrum.
term code: D013053

Spectrum Analysis, Raman
type: DefinedTerm
description: Analysis of the intensity of Raman scattering of monochromatic light as a function of frequency of the scattered light.
term code: D013059

Photoelectron Spectroscopy
type: DefinedTerm
description: The study of the energy of electrons ejected from matter by the photoelectric effect, i.e., as a direct result of absorption of energy from electromagnetic radiation. As the energies of the electrons are characteristic of a specific element, the measurement of the energy of these electrons is a technique used to determine the chemical composition of surfaces.
term code: D056951

diffusion
type: DefinedTerm
description: The spontaneous movement and scattering of particles (atoms and molecules), of liquid, gases, and solids.
term code: 2186

glass
type: DefinedTerm
description: A hard, amorphous, inorganic, usually transparent, brittle substance made by fusing silicates, sometimes borates and phosphates, with certain basic oxides and then rapidly cooling to prevent crystallization.
term code: 3678

melting
type: DefinedTerm
description: A change of the state of a substance from the solid phase to the liquid phase. Also known as fusion.
term code: 5148

tempering (metalwork)
type: DefinedTerm
term code: p4133